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Synthesis, oligomerization and catalytic studies of a redox-active Ni(4)-cubane: a detailed mechanistic investigation
A robust tetrameric nickel complex [Ni(4)((O(al)(−))(2)L-Me)(4)(s)(4)] (3) (s = solvent) with cubane-like Ni(4)O(4) core topology was isolated as a light greenish-orange crystalline solid in excellent yield. The mechanism of formation of 3 involving the two chloride-containing precursors [Ni(4)((O(a...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034354/ https://www.ncbi.nlm.nih.gov/pubmed/35480420 http://dx.doi.org/10.1039/d1ra03071j |