Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts

This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance.

Detalles Bibliográficos
Autores principales: Sallio, Romain, Payard, Pierre-Adrien, Pakulski, Paweł, Diachenko, Iryna, Fabre, Indira, Berteina-Raboin, Sabine, Colas, Cyril, Ciofini, Ilaria, Grimaud, Laurence, Gillaizeau, Isabelle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036411/
https://www.ncbi.nlm.nih.gov/pubmed/35481165
http://dx.doi.org/10.1039/d1ra02305e
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author Sallio, Romain
Payard, Pierre-Adrien
Pakulski, Paweł
Diachenko, Iryna
Fabre, Indira
Berteina-Raboin, Sabine
Colas, Cyril
Ciofini, Ilaria
Grimaud, Laurence
Gillaizeau, Isabelle
author_facet Sallio, Romain
Payard, Pierre-Adrien
Pakulski, Paweł
Diachenko, Iryna
Fabre, Indira
Berteina-Raboin, Sabine
Colas, Cyril
Ciofini, Ilaria
Grimaud, Laurence
Gillaizeau, Isabelle
author_sort Sallio, Romain
collection PubMed
description This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance.
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spelling pubmed-90364112022-04-26 Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts Sallio, Romain Payard, Pierre-Adrien Pakulski, Paweł Diachenko, Iryna Fabre, Indira Berteina-Raboin, Sabine Colas, Cyril Ciofini, Ilaria Grimaud, Laurence Gillaizeau, Isabelle RSC Adv Chemistry This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance. The Royal Society of Chemistry 2021-04-28 /pmc/articles/PMC9036411/ /pubmed/35481165 http://dx.doi.org/10.1039/d1ra02305e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Sallio, Romain
Payard, Pierre-Adrien
Pakulski, Paweł
Diachenko, Iryna
Fabre, Indira
Berteina-Raboin, Sabine
Colas, Cyril
Ciofini, Ilaria
Grimaud, Laurence
Gillaizeau, Isabelle
Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts
title Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts
title_full Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts
title_fullStr Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts
title_full_unstemmed Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts
title_short Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts
title_sort copper-catalyzed transformation of alkyl nitriles to n-arylacetamide using diaryliodonium salts
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036411/
https://www.ncbi.nlm.nih.gov/pubmed/35481165
http://dx.doi.org/10.1039/d1ra02305e
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