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Probing the ionic structure of FLiNaK–ZrF(4) salt mixtures by solid-state NMR

In this study, by applying (19)F, (23)Na and (7)Li high-resolution NMR methods, the evolution of the [Zr(x)F(y)](4x−y) local ionic structures in FLiNaK–ZrF(4) salt mixtures were elucidated. K(3)ZrF(7), Na(3)ZrF(7) and Na(7)Zr(6)F(31) crystal phases were identified when the melt salts were being soli...

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Detalles Bibliográficos
Autores principales: Lan, Rongshan, Liu, Yiyang, Han, Ling, Yang, Jing, Yin, Huiqin, Ge, Min, Fu, Xiaobin, Liu, Hongtao, Qian, Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036575/
https://www.ncbi.nlm.nih.gov/pubmed/35479022
http://dx.doi.org/10.1039/d1ra04629b