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Probing the ionic structure of FLiNaK–ZrF(4) salt mixtures by solid-state NMR
In this study, by applying (19)F, (23)Na and (7)Li high-resolution NMR methods, the evolution of the [Zr(x)F(y)](4x−y) local ionic structures in FLiNaK–ZrF(4) salt mixtures were elucidated. K(3)ZrF(7), Na(3)ZrF(7) and Na(7)Zr(6)F(31) crystal phases were identified when the melt salts were being soli...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036575/ https://www.ncbi.nlm.nih.gov/pubmed/35479022 http://dx.doi.org/10.1039/d1ra04629b |