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Highly efficient and tunable visible-light-catalytic synthesis of 2,5-diformylfuran using HBr and molecular oxygen

This paper discloses that inexpensive hydrobromic acid (HBr) is active and highly selective to the photo-oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) with dioxygen (O(2)) or even with water under visible light illumination, which can achieve the highest 89.1% DFF yield in DM...

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Detalles Bibliográficos
Autores principales: Hu, Wenwei, She, Jialuo, Fu, Zaihui, Yang, Bo, Zhang, Huanhuan, Jiang, Dabo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036589/
https://www.ncbi.nlm.nih.gov/pubmed/35479798
http://dx.doi.org/10.1039/d1ra00865j