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Substitution reactivity and structural variability induced by tryptamine on the biomimetic rhenium tricarbonyl complex

A series of seven fac-[Re(CO)(3)(5Me-Sal-Trypt)(L)] complexes containing tryptamine on the N,O 5-methyl-salicylidene bidentate ligand backbone and where L is MeOH, Py, Imi, DMAP, PPh(3) coordinated to the 6th position have been studied, including the formation of a dinuclear Re(2) cluster. The cryst...

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Detalles Bibliográficos
Autores principales: Jacobs, Frederick J. F., Venter, Gertruida J. S., Fourie, Eleanor, Kroon, Robin E., Brink, Alice
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036643/
https://www.ncbi.nlm.nih.gov/pubmed/35479015
http://dx.doi.org/10.1039/d1ra03750a