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Alteration of intramolecular electronic transition via deboronation of carbazole-based o-carboranyl compound and intriguing ‘turn-on’ emissive variation

The conversion of closo-o-carborane–containing compounds to the nido-o-species via deboronation causes photophysical changes that could be used for sensing applications. 9-Methyl-9H-carbazole–based closo- (closo-Cz) and nido-o-carboranyl (nido-Cz) compounds were prepared and fully characterised by m...

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Detalles Bibliográficos
Autores principales: Lee, Seok Ho, Mun, Min Sik, Kim, Mingi, Lee, Ji Hye, Hwang, Hyonseok, Lee, Wonchul, Lee, Kang Mun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036662/
https://www.ncbi.nlm.nih.gov/pubmed/35479040
http://dx.doi.org/10.1039/d1ra03716a