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A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma

The focus of this article rests on our discovery that a water-soluble polymer could be cross-linked to form a gel using a novel Green Chemistry gelation method: the microwave-induced in-liquid-plasma (MILP) method that requires neither a cross-linking agent nor an initiator as are required in the co...

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Autores principales: Horikoshi, Satoshi, Sawada, Seiya, Serpone, Nick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036679/
https://www.ncbi.nlm.nih.gov/pubmed/35479003
http://dx.doi.org/10.1039/d1ra03007h
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author Horikoshi, Satoshi
Sawada, Seiya
Serpone, Nick
author_facet Horikoshi, Satoshi
Sawada, Seiya
Serpone, Nick
author_sort Horikoshi, Satoshi
collection PubMed
description The focus of this article rests on our discovery that a water-soluble polymer could be cross-linked to form a gel using a novel Green Chemistry gelation method: the microwave-induced in-liquid-plasma (MILP) method that requires neither a cross-linking agent nor an initiator as are required in the conventional chemical method. For instance, the water-soluble polyvinyl pyrrolidone (PVP) polymer was gelled by MILP plasma irradiation within a few minutes without using toxic cross-linking agents and initiators. As well, the hydrophobic dimethylpolysiloxane macromolecule was dispersed in aqueous media to a colloidal sol, which could then also be easily gelled under MILP irradiation conditions within a few minutes, in comparison to the conventional method that often requires several hours to days for gelation to occur in the presence of cross-linking agents and initiators. The viscosity of the MILP silicone gel was greater than a similar gel formed by the conventional method. In contrast, the viscosity of the MILP-formed PVP gel was lower than the viscosity of the PVP gel obtained from the conventional method. Gels were characterized by (13)C-NMR spectrometry, FT-IR spectroscopy, SEM microscopy, viscosity measurements, and dynamic light scattering for particle size distributions. Plausible mechanistic stages for the two gelation occurrences have been inferred as involving the synergistic effects from microwaves, together with the sound waves (cavitation microbubbles), heat, UV and ˙OH radicals resulting from the microwave-generated in-liquid-plasma.
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spelling pubmed-90366792022-04-26 A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma Horikoshi, Satoshi Sawada, Seiya Serpone, Nick RSC Adv Chemistry The focus of this article rests on our discovery that a water-soluble polymer could be cross-linked to form a gel using a novel Green Chemistry gelation method: the microwave-induced in-liquid-plasma (MILP) method that requires neither a cross-linking agent nor an initiator as are required in the conventional chemical method. For instance, the water-soluble polyvinyl pyrrolidone (PVP) polymer was gelled by MILP plasma irradiation within a few minutes without using toxic cross-linking agents and initiators. As well, the hydrophobic dimethylpolysiloxane macromolecule was dispersed in aqueous media to a colloidal sol, which could then also be easily gelled under MILP irradiation conditions within a few minutes, in comparison to the conventional method that often requires several hours to days for gelation to occur in the presence of cross-linking agents and initiators. The viscosity of the MILP silicone gel was greater than a similar gel formed by the conventional method. In contrast, the viscosity of the MILP-formed PVP gel was lower than the viscosity of the PVP gel obtained from the conventional method. Gels were characterized by (13)C-NMR spectrometry, FT-IR spectroscopy, SEM microscopy, viscosity measurements, and dynamic light scattering for particle size distributions. Plausible mechanistic stages for the two gelation occurrences have been inferred as involving the synergistic effects from microwaves, together with the sound waves (cavitation microbubbles), heat, UV and ˙OH radicals resulting from the microwave-generated in-liquid-plasma. The Royal Society of Chemistry 2021-07-12 /pmc/articles/PMC9036679/ /pubmed/35479003 http://dx.doi.org/10.1039/d1ra03007h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Horikoshi, Satoshi
Sawada, Seiya
Serpone, Nick
A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma
title A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma
title_full A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma
title_fullStr A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma
title_full_unstemmed A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma
title_short A novel green chemistry gelation method for polyvinyl pyrrolidone (PVP) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma
title_sort novel green chemistry gelation method for polyvinyl pyrrolidone (pvp) and dimethylpolysiloxane (silicone): microwave-induced in-liquid-plasma
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036679/
https://www.ncbi.nlm.nih.gov/pubmed/35479003
http://dx.doi.org/10.1039/d1ra03007h
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