Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors

Ruthenium(iv) N-confused porphyrin μ-oxo-bridged complexes were synthesized via oxidative dimerization of a ruthenium(ii) N-confused porphyrin complex using 2,2,6,6-tetramethylpiperidine 1-oxyl. The deformed core planes in the dimers conferred a relatively high ring rotational barrier of ca. 16 kcal...

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Detalles Bibliográficos
Autores principales: Iwanaga, Osamu, Fukuyama, Kazuki, Mori, Shigeki, Song, Jun Tae, Ishihara, Tatsumi, Miyazaki, Takaaki, Ishida, Masatoshi, Furuta, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036866/
https://www.ncbi.nlm.nih.gov/pubmed/35481054
http://dx.doi.org/10.1039/d1ra05063j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036866/
https://www.ncbi.nlm.nih.gov/pubmed/35481054
http://dx.doi.org/10.1039/d1ra05063j

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