Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors

Ruthenium(iv) N-confused porphyrin μ-oxo-bridged complexes were synthesized via oxidative dimerization of a ruthenium(ii) N-confused porphyrin complex using 2,2,6,6-tetramethylpiperidine 1-oxyl. The deformed core planes in the dimers conferred a relatively high ring rotational barrier of ca. 16 kcal...

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Detalles Bibliográficos
Autores principales: Iwanaga, Osamu, Fukuyama, Kazuki, Mori, Shigeki, Song, Jun Tae, Ishihara, Tatsumi, Miyazaki, Takaaki, Ishida, Masatoshi, Furuta, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036866/
https://www.ncbi.nlm.nih.gov/pubmed/35481054
http://dx.doi.org/10.1039/d1ra05063j
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author Iwanaga, Osamu
Fukuyama, Kazuki
Mori, Shigeki
Song, Jun Tae
Ishihara, Tatsumi
Miyazaki, Takaaki
Ishida, Masatoshi
Furuta, Hiroyuki
author_facet Iwanaga, Osamu
Fukuyama, Kazuki
Mori, Shigeki
Song, Jun Tae
Ishihara, Tatsumi
Miyazaki, Takaaki
Ishida, Masatoshi
Furuta, Hiroyuki
author_sort Iwanaga, Osamu
collection PubMed
description Ruthenium(iv) N-confused porphyrin μ-oxo-bridged complexes were synthesized via oxidative dimerization of a ruthenium(ii) N-confused porphyrin complex using 2,2,6,6-tetramethylpiperidine 1-oxyl. The deformed core planes in the dimers conferred a relatively high ring rotational barrier of ca. 16 kcal mol(−1). Rotation of the complexes was controlled by protonating the peripheral nitrogen.
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spelling pubmed-90368662022-04-26 Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors Iwanaga, Osamu Fukuyama, Kazuki Mori, Shigeki Song, Jun Tae Ishihara, Tatsumi Miyazaki, Takaaki Ishida, Masatoshi Furuta, Hiroyuki RSC Adv Chemistry Ruthenium(iv) N-confused porphyrin μ-oxo-bridged complexes were synthesized via oxidative dimerization of a ruthenium(ii) N-confused porphyrin complex using 2,2,6,6-tetramethylpiperidine 1-oxyl. The deformed core planes in the dimers conferred a relatively high ring rotational barrier of ca. 16 kcal mol(−1). Rotation of the complexes was controlled by protonating the peripheral nitrogen. The Royal Society of Chemistry 2021-07-13 /pmc/articles/PMC9036866/ /pubmed/35481054 http://dx.doi.org/10.1039/d1ra05063j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Iwanaga, Osamu
Fukuyama, Kazuki
Mori, Shigeki
Song, Jun Tae
Ishihara, Tatsumi
Miyazaki, Takaaki
Ishida, Masatoshi
Furuta, Hiroyuki
Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors
title Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors
title_full Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors
title_fullStr Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors
title_full_unstemmed Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors
title_short Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors
title_sort ruthenium(iv) n-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036866/
https://www.ncbi.nlm.nih.gov/pubmed/35481054
http://dx.doi.org/10.1039/d1ra05063j
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