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Mechanistic insights into dioxygen activation by a manganese corrole complex: a broken-symmetry DFT study
The Mn–oxygen species have been implicated as key intermediates in various Mn-mediated oxidation reactions. However, artificial oxidants were often used for the synthesis of the Mn–oxygen intermediates. Remarkably, the Mn(v)–oxo and Mn(iv)–peroxo species have been observed in the activation of O(2)...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036905/ https://www.ncbi.nlm.nih.gov/pubmed/35481047 http://dx.doi.org/10.1039/d1ra02722k |