Cargando…

Mechanistic insights into dioxygen activation by a manganese corrole complex: a broken-symmetry DFT study

The Mn–oxygen species have been implicated as key intermediates in various Mn-mediated oxidation reactions. However, artificial oxidants were often used for the synthesis of the Mn–oxygen intermediates. Remarkably, the Mn(v)–oxo and Mn(iv)–peroxo species have been observed in the activation of O(2)...

Descripción completa

Detalles Bibliográficos
Autores principales: Yu, Jiangfeng, Lai, Wenzhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036905/
https://www.ncbi.nlm.nih.gov/pubmed/35481047
http://dx.doi.org/10.1039/d1ra02722k

Ejemplares similares