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One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)(3) with common alcohols

A series of gradient copolymers were synthesized by the ruthenium-catalyzed living radical polymerization (LRP) of methyl acrylate (MA) and aliphatic alcohols using aluminum acetylacetonate Al(acac)(3). In this polymerization system, Al(acac)(3) was successfully used not only as an additive for the...

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Detalles Bibliográficos
Autores principales: Huynh, Tam Thi-Thanh, Kim, Si Eun, Kim, Soon Cheon, Kim, Jin Chul, Park, Young Il, Jeong, Ji-Eun, Yeo, Hyeonuk, Lee, Sang-Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037116/
https://www.ncbi.nlm.nih.gov/pubmed/35479477
http://dx.doi.org/10.1039/d1ra04595d