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Transition-metal-free synthesis of aryl 1-thioglycosides with arynes at room temperature

A mild, convenient and transition-metal-free protocol for the synthesis of aryl 1-thioglycosides is presented via arynes generated in situ combined with glycosyl thiols in the presence of TBAF(tBuOH)(4). The methodology provides a general and efficient way to prepare a series of functionalized thiog...

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Detalles Bibliográficos
Autores principales: Liu, Yao, Yu, Xiao-Bing, Zhang, Xiang-Mei, Zhong, Qian, Liao, Li-Hua, Yan, Nan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037310/
https://www.ncbi.nlm.nih.gov/pubmed/35479995
http://dx.doi.org/10.1039/d1ra04013h