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Strongly reduced lattice thermal conductivity in Sn-doped rare-earth (M) filled skutterudites M(x)Co(4)Sb(12−y)Sn(y), promoted by Sb–Sn disordering and phase segregation

CoSb(3) thermoelectric skutterudite has been filled with rare-earth metals (M = La, Ce, Yb) and partially doped with Sn in specimens of M(x)Co(4)Sb(12−y)Sn(y) stoichiometry. This has been achieved under high-pressure conditions at 3.5 GPa in a piston-cylinder hydrostatic press. A structural investig...

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Detalles Bibliográficos
Autores principales: Gainza, J., Serrano-Sánchez, F., Nemes, N. M., Dura, O. J., Martínez, J. L., Fauth, F., Alonso, J. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037351/
https://www.ncbi.nlm.nih.gov/pubmed/35479462
http://dx.doi.org/10.1039/d1ra04270j