Copper(i)-catalyzed radical carboamination reaction of 8-aminoquinoline-oriented buteneamides with chloroform: synthesis of-β-lactams

A novel Cu(CH(3)CN)(4)PF(6)-catalyzed carboamination reaction of 8-aminoquinoline-oriented buteneamides with chloroform to afford 4-(2,2,2-trichloroethyl)-β-lactams is described. The reaction proceeded at 110 °C in air with di-t-butyl peroxide. Preliminary studies indicated that the reaction undergo...

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Detalles Bibliográficos
Autores principales: Gan, Zixu, Zhang, Ke, Shi, Peng, Zhao, Yingsheng, Zeng, Runsheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037986/
https://www.ncbi.nlm.nih.gov/pubmed/35480755
http://dx.doi.org/10.1039/d1ra05233k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037986/
https://www.ncbi.nlm.nih.gov/pubmed/35480755
http://dx.doi.org/10.1039/d1ra05233k

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