Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand

Combining a bulky bis(amide) and a reactive one-coordinate TMP (2,2,6,6-tetramethylpiperidide) ligand, a new mixed K/Zn heteroleptic base has been developed for regioselective zincation of fluoroarenes. This special ligand set allows for trapping and structural authentication of the first intermedia...

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Detalles Bibliográficos
Autores principales: Mastropierro, Pasquale, Kennedy, Alan R., Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040423/
https://www.ncbi.nlm.nih.gov/pubmed/35403647
http://dx.doi.org/10.1039/d2cc00979j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040423/
https://www.ncbi.nlm.nih.gov/pubmed/35403647
http://dx.doi.org/10.1039/d2cc00979j

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