Copper(ii)-catalyzed and acid-promoted highly regioselective oxidation of tautomerizable C(sp(3))–H bonds adjacent to 3,4-dihydroisoquinolines using air (O(2)) as a clean oxidant

A mild, efficient and eco-friendly method for the oxidation of 1-Bn-DHIQs to 1-Bz-DHIQs without concomitant excessive oxidation of 1-Bz-DHIQs to 1-Bz-IQs is very important for the syntheses of 1-Bz-DHIQ alkaloids and analogues. In this article, we developed a novel Cu(ii)-catalyzed and acid-promoted...

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Detalles Bibliográficos
Autores principales: He, Yun-Gang, Huang, Yong-Kang, Fan, Qi-Qi, Zheng, Bo, Luo, Yong-Qiang, Zhu, Xing-Liang, Shi, Xiao-Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040818/
https://www.ncbi.nlm.nih.gov/pubmed/35479555
http://dx.doi.org/10.1039/d1ra05671a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040818/
https://www.ncbi.nlm.nih.gov/pubmed/35479555
http://dx.doi.org/10.1039/d1ra05671a

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