Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids

Fast (60 kHz) magic angle spinning solid-state NMR allows very sensitive proton detection in highly paramagnetic organometallic powders. We showcase this technique with the complete assignment of (1)H and (13)C resonances in a high-spin Fe(ii) polymerisation catalyst with less than 2 mg of sample at...

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Autores principales: Blahut, Jan, Benda, Ladislav, Lejeune, Arthur L., Sanders, Kevin J., Burcher, Benjamin, Jeanneau, Erwann, Proriol, David, Catita, Leonor, Breuil, Pierre-Alain R., Quoineaud, Anne-Agathe, Pell, Andrew J., Pintacuda, Guido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040908/
https://www.ncbi.nlm.nih.gov/pubmed/35479571
http://dx.doi.org/10.1039/d1ra04110j
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author Blahut, Jan
Benda, Ladislav
Lejeune, Arthur L.
Sanders, Kevin J.
Burcher, Benjamin
Jeanneau, Erwann
Proriol, David
Catita, Leonor
Breuil, Pierre-Alain R.
Quoineaud, Anne-Agathe
Pell, Andrew J.
Pintacuda, Guido
author_facet Blahut, Jan
Benda, Ladislav
Lejeune, Arthur L.
Sanders, Kevin J.
Burcher, Benjamin
Jeanneau, Erwann
Proriol, David
Catita, Leonor
Breuil, Pierre-Alain R.
Quoineaud, Anne-Agathe
Pell, Andrew J.
Pintacuda, Guido
author_sort Blahut, Jan
collection PubMed
description Fast (60 kHz) magic angle spinning solid-state NMR allows very sensitive proton detection in highly paramagnetic organometallic powders. We showcase this technique with the complete assignment of (1)H and (13)C resonances in a high-spin Fe(ii) polymerisation catalyst with less than 2 mg of sample at natural abundance.
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spelling pubmed-90409082022-04-26 Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids Blahut, Jan Benda, Ladislav Lejeune, Arthur L. Sanders, Kevin J. Burcher, Benjamin Jeanneau, Erwann Proriol, David Catita, Leonor Breuil, Pierre-Alain R. Quoineaud, Anne-Agathe Pell, Andrew J. Pintacuda, Guido RSC Adv Chemistry Fast (60 kHz) magic angle spinning solid-state NMR allows very sensitive proton detection in highly paramagnetic organometallic powders. We showcase this technique with the complete assignment of (1)H and (13)C resonances in a high-spin Fe(ii) polymerisation catalyst with less than 2 mg of sample at natural abundance. The Royal Society of Chemistry 2021-09-29 /pmc/articles/PMC9040908/ /pubmed/35479571 http://dx.doi.org/10.1039/d1ra04110j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Blahut, Jan
Benda, Ladislav
Lejeune, Arthur L.
Sanders, Kevin J.
Burcher, Benjamin
Jeanneau, Erwann
Proriol, David
Catita, Leonor
Breuil, Pierre-Alain R.
Quoineaud, Anne-Agathe
Pell, Andrew J.
Pintacuda, Guido
Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids
title Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids
title_full Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids
title_fullStr Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids
title_full_unstemmed Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids
title_short Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids
title_sort proton-detected fast-magic-angle spinning nmr of paramagnetic inorganic solids
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040908/
https://www.ncbi.nlm.nih.gov/pubmed/35479571
http://dx.doi.org/10.1039/d1ra04110j
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