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Halogen-containing heteroaromatic carbenes of the 1,2,4-triazole series and their transformations

A series of new stable halogenated carbenes, 1-tert-butyl-3,4-diaryl-1,2,4-triazol-5-ylidenes, has been synthesized. According to quantum chemical calculations, 4-(2,3,4-trifluorophenyl)-substituted 1-tert-butyl-3,4-diaryl-1,2,4-triazol-5-ylidene is the least basic in comparison with the known steri...

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Detalles Bibliográficos
Autores principales: Glinyanaya, Nataliya V., Rayenko, Gennady F., Korotkikh, Nikolai I., Rusanov, Eduard B., Ryabitsky, Alexey B., Shvaika, Oles P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041323/
https://www.ncbi.nlm.nih.gov/pubmed/35498946
http://dx.doi.org/10.1039/d1ra04337d