Hybrid compound based on diethylenetriaminecopper(ii) cations and scarce V-monosubstituted β-octamolybdate as water oxidation catalyst

Herein, we report on a new hybrid compound (NH(4)){[Cu(dien)(H(2)O)(2)](2)[β-VMo(7)O(26)]}·1.5H(2)O (1), where dien = diethylenetriamine, containing an extremely rare mixed-metal pseudo-octamolybdate cluster. An ex situ EPR spectroscopy provided insights into the formation of paramagnetic species in...

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Detalles Bibliográficos
Autores principales: Buvailo, Halyna I., Makhankova, Valeriya G., Kokozay, Vladimir N., Omelchenko, Iryna V., Shishkina, Svitlana V., Bieńko, Alina, Pavliuk, Mariia V., Shylin, Sergii I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041742/
https://www.ncbi.nlm.nih.gov/pubmed/35495520
http://dx.doi.org/10.1039/d1ra05030c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041742/
https://www.ncbi.nlm.nih.gov/pubmed/35495520
http://dx.doi.org/10.1039/d1ra05030c

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