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Revisiting the covalent nature of halogen bonding: a polarized three-center four-electron bond
As an important intermolecular interaction, halogen bonding has been studied extensively, but its nature still suffers from controversy without one uniform essence. Electrostatics, charge transfer, polarization and dispersion are emphasized, but the covalent nature is usually overlooked except for t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042191/ https://www.ncbi.nlm.nih.gov/pubmed/35493597 http://dx.doi.org/10.1039/d1ra05695f |