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DIBALH: from known fundamental to an unusual reaction; chemoselective partial reduction of tertiary amides in the presence of esters

This study presents a quick and reliable approach to the chemoselective partial reduction of tertiary amides to aldehydes in the presence of readily reducible ester groups using commercial DIBALH reagent. Moreover, the developed method was also extended to multi-functional molecules bearing ester mo...

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Detalles Bibliográficos
Autores principales: Heo, Yu Jin, Kim, Hyun Tae, Jaladi, Ashok Kumar, An, Duk Keun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042244/
https://www.ncbi.nlm.nih.gov/pubmed/35497556
http://dx.doi.org/10.1039/d1ra06279d