Regioselective formylation of rhenium-oxo and gold corroles: substituent effects on optical spectra and redox potentials

Vilsmeier–Haack formylation of ReO and Au meso-triarylcorroles over 16–18 hours affords moderate to good yields (47–65%) of the ReO-3-formyl and Au-3,17-diformyl derivatives in a highly regioselective manner. Formylation was found to effect substantial upshifts for redox potentials (especially the r...

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Detalles Bibliográficos
Autores principales: Einrem, Rune F., Jonsson, Einar Torfi, Teat, Simon J., Settineri, Nicholas S., Alemayehu, Abraham B., Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042328/
https://www.ncbi.nlm.nih.gov/pubmed/35497316
http://dx.doi.org/10.1039/d1ra05525a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042328/
https://www.ncbi.nlm.nih.gov/pubmed/35497316
http://dx.doi.org/10.1039/d1ra05525a

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