Site-selective unidirectional benzylic sp(3) C–H oxidation of dodecahydrotriphenylene with RuCl(3)–NaIO(4): formation of benzylic ketones

Dodecahydrotriphenylene, a higher homologue of trindane chemoselectively undergoes unidirectional benzylic sp(3) C–H oxidation and the central benzene ring remains intact unlike that in trindane under similar reaction conditions. RuO(4) which generally attacks sp(2) C–H to form oxidative products is...

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Detalles Bibliográficos
Autores principales: Bhatt, Gaurang J., Deota, Pradeep T., Upadhyay, Deepak, Jha, Prafulla K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042685/
https://www.ncbi.nlm.nih.gov/pubmed/35494771
http://dx.doi.org/10.1039/d1ra06897k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042685/
https://www.ncbi.nlm.nih.gov/pubmed/35494771
http://dx.doi.org/10.1039/d1ra06897k

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