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Ferrocenium complex aided O-glycosylation of glycosyl halides

A new strategy for the activation of glycosyl halide donors to be utilized in glycosylation reactions is presented, utilizing the ferrocenium (Fc) complexes [FcB(OH)(2)]SbF(6) and FcBF(4) as promoters. The scope of the new system has been investigated using glycosyl chloride and glycosyl fluoride do...

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Detalles Bibliográficos
Autores principales: Talasila, Deva Saroja, Bauer, Eike B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043573/
https://www.ncbi.nlm.nih.gov/pubmed/35494397
http://dx.doi.org/10.1039/d1ra05788j