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Nickel(ii)-catalyzed reductive silylation of alkenyl methyl ethers for the synthesis of alkyl silanes

A new one pot protocol has been developed for the reductive silylation of alkenyl methyl ethers using Et(3)Si–BPin and HSiEt(3) with nickel(ii) catalyst. Styrene type methyl ethers, multi-substituted vinyl methyl ethers, heterocycles and unconjugated vinyl ethers are all tolerated to form alkyl sila...

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Detalles Bibliográficos
Autores principales: Qiu, Xiaodong, Zhou, Li, Wang, Haoran, Lu, Lingyi, Ling, Yong, Zhang, Yanan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043817/
https://www.ncbi.nlm.nih.gov/pubmed/35496447
http://dx.doi.org/10.1039/d1ra07238b