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Long range deuterium isotope effects on (13)C NMR chemical shifts of 2-alkanones in CD(3)OD solutions of imidazolium acetate ionic liquids

Deuterium isotope substitution in one part of a molecule could produce a significant effect on chemical shifts of neighbouring nuclei as well as on nuclei, located far from the site of replacement. To estimate how far this influence could extend the reaction of proton–deuterium exchange of several 2...

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Detalles Bibliográficos
Autores principales: Shahkhatuni, Astghik A., Shahkhatuni, Aleksan G., Harutyunyan, Arpine S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044476/
https://www.ncbi.nlm.nih.gov/pubmed/35492497
http://dx.doi.org/10.1039/d1ra07232c