Enantio- and regioselective asymmetric allylic substitution using a chiral aminophosphinite ruthenium complex: an experimental and theoretical investigation

The design and synthesis of a new chiral aminophosphinite-ligated ruthenium complex is described. The ruthenium complex, [Ru(AMP)(2)(CH(3)CN)(2)][BPh(4)](2) {AMP = (S)-tert-butyl 1-(diphenylphosphinooxy)-3-methylbutan-2-ylcarbamate}, has been found to catalyze nucleophilic addition of phenol and car...

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Detalles Bibliográficos
Autores principales: Jena, Rajesh K., Das, Dhiraj
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044493/
https://www.ncbi.nlm.nih.gov/pubmed/35492500
http://dx.doi.org/10.1039/d1ra06824e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044493/
https://www.ncbi.nlm.nih.gov/pubmed/35492500
http://dx.doi.org/10.1039/d1ra06824e

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