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Reductive C(sp(3))–C(sp(3)) homo-coupling of benzyl or allyl halides with H(2) using a water-soluble electron storage catalyst

This paper reports the first example of a reductive C(sp(3))–C(sp(3)) homo-coupling of benzyl/allyl halides in aqueous solution by using H(2) as an electron source {turnover numbers (TONs) = 0.5–2.3 for 12 h}. This homo-coupling reaction, promoted by visible light, is catalysed by a water-soluble el...

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Detalles Bibliográficos
Autores principales: Yatabe, Takeshi, Futakuchi, Sayaka, Miyazawa, Keishi, Shimauchi, Daiki, Takahashi, Yukina, Yoon, Ki-Seok, Nakai, Hidetaka, Ogo, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044531/
https://www.ncbi.nlm.nih.gov/pubmed/35492457
http://dx.doi.org/10.1039/d1ra08596d