Breaking thiacalix[4]arene into pieces – a novel synthetic approach to higher calixarenes bearing mixed (–S–, –CH(2)–) bridges

A novel approach to calix[5–7]arenes possessing mixed (S and CH(2)) bridges within the skeleton is based on the reaction of thiacalix[4]arene monosulfoxide with BuLi leading to a linear phenolic tetramer in essentially quantitative yield. This key intermediate is then cyclized with suitable building...

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Detalles Bibliográficos
Autores principales: Kaiser, Lukáš, Landovský, Tomáš, Salvadori, Karolína, Eigner, Václav, Dvořáková, Hana, Lhoták, Pavel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044755/
https://www.ncbi.nlm.nih.gov/pubmed/35494352
http://dx.doi.org/10.1039/d1ra07464d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044755/
https://www.ncbi.nlm.nih.gov/pubmed/35494352
http://dx.doi.org/10.1039/d1ra07464d

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