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Synthesis and study of C-substituted methylthio derivatives of cobalt bis(dicarbollide)

The C-methylthio derivatives of cobalt bis(dicarbollide) were synthesized by reaction of anhydrous CoCl(2) with nido-carborane [7-MeS-7,8-C(2)B(9)H(11)](−) and isolated as a mixture of rac-[1,1′-(MeS)(2)-3,3′-Co(1,2-C(2)B(9)H(10))(2)](−) and meso-[1,2′-(MeS)(2)-3,3′-Co(1,2-C(2)B(9)H(10))(2)](−) isom...

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Detalles Bibliográficos
Autores principales: Stogniy, Marina Yu., Kazheva, Olga N., Chudak, Denis M., Shilov, Gennady V., Filippov, Oleg A., Sivaev, Igor B., Kravchenko, Andrey V., Starodub, Vladimir A., Buravov, Lev I., Bregadze, Vladimir I., Dyachenko, Oleg A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9048485/
https://www.ncbi.nlm.nih.gov/pubmed/35496089
http://dx.doi.org/10.1039/c9ra08551c