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A dielectric and spectrophotometric study of the tautomerization of 2-hydroxypyridine and 2-mercaptopyridine in water
The basic ionization (pk(1)) and acidic ionization (pk(2)) constants and equilibrium constant (K(T)) of 2HPy and 2MPy were determined. The pk(1)(s) of their N- and X-methyl derivatives (X = O, S) were also determined. The equilibrium constant of 2MPy is approximately 60 times greater than its oxygen...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9048638/ https://www.ncbi.nlm.nih.gov/pubmed/35494609 http://dx.doi.org/10.1039/c9ra08392h |