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Tailoring the AlCl(3)/iPr(2)O/Et(2)O initiation system for highly reactive polyisobutylene synthesis in pure n-hexane
This paper reports the flow synthesis of highly reactive polyisobutylenes (HRPIBs) in pure n-hexane using properly prepared AlCl(3)·Et(2)O crystals in conjunction with AlCl(3)·iPr(2)O solution as coinitiators. By preparing AlCl(3)·iPr(2)O solution and AlCl(3)·Et(2)O crystals separately, the cationic...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049001/ https://www.ncbi.nlm.nih.gov/pubmed/35498282 http://dx.doi.org/10.1039/c9ra11003h |