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Photochemical anti–syn isomerization around the –N–N[double bond, length as m-dash] bond in heterocyclic imines

EPR and NMR experiments on a quinazolinone-based Schiff's base in DMSO solution showed that irradiation with UV light (365 nm) leads to photochemically-induced isomerization from the anti- to the higher-energy syn-form around the –N–N[double bond, length as m-dash] linkage. The anti- to syn-iso...

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Detalles Bibliográficos
Autores principales: Hricovíni, Michal, Asher, James, Hricovíni, Miloš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049245/
https://www.ncbi.nlm.nih.gov/pubmed/35497446
http://dx.doi.org/10.1039/c9ra10730d