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Photochemical anti–syn isomerization around the –N–N[double bond, length as m-dash] bond in heterocyclic imines
EPR and NMR experiments on a quinazolinone-based Schiff's base in DMSO solution showed that irradiation with UV light (365 nm) leads to photochemically-induced isomerization from the anti- to the higher-energy syn-form around the –N–N[double bond, length as m-dash] linkage. The anti- to syn-iso...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049245/ https://www.ncbi.nlm.nih.gov/pubmed/35497446 http://dx.doi.org/10.1039/c9ra10730d |