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Crystallization of colourless hexanitratoneptunate(iv) with anhydrous H(+) countercations trapped in a hydrogen bonded polymer with diamide linkers

Colourless crystalline compounds of centrosymmetric [Np(NO(3))(6)](2−) were yielded from 3 M HNO(3) aq in the presence of double-headed 2-pyrrolidone derivatives (L). In the obtained crystal structures, H(+) was also involved as a countercation to compensate for the negative charge of [Np(NO(3))(6)]...

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Detalles Bibliográficos
Autores principales: Takao, Koichiro, März, Juliane, Matsuoka, Moe, Mashita, Takanori, Kazama, Hiroyuki, Tsushima, Satoru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049546/
https://www.ncbi.nlm.nih.gov/pubmed/35497425
http://dx.doi.org/10.1039/c9ra10090c