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A 3D open-framework iron hydrogenophosphate showing high proton conductance under water and aqua-ammonia vapor

Herein we report the first example of the proton conductivity of an open-framework metal phosphate (NH(3)(CH(2))(3)NH(3))(2)–[Fe(4)(OH)(3)(HPO(4))(2)(PO(4))(3)]·4H(2)O under aqua-ammonia vapor. Its optimized proton conductivity is 5 × 10(−2) S cm(−1) at 313 K and aqua-ammonium vapor from 1 M NH(3)·H...

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Detalles Bibliográficos
Autores principales: Zhao, Hai-rong, Jia, Yin, Gu, Yi, He, Feng-yun, Zhang, Kai-ming, Tian, Zheng-fang, Liu, Jian-Lan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050034/
https://www.ncbi.nlm.nih.gov/pubmed/35496546
http://dx.doi.org/10.1039/d0ra00270d