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Enantioselective hydrosilylation of unsaturated carbon–heteroatom bonds (C[double bond, length as m-dash]N, C[double bond, length as m-dash]O) catalyzed by [Ru–S] complexes: a theoretical study
A detailed theoretical study on the mechanism of enanthioselective hydrosilylation of imines and ketones catalyzed by the ruthenium(ii) thiolate catalyst [Ru–S] ([L*-Ru(SDmp)](+)[BAr(4)(F)](−)) with a chiral monodentate phosphine ligand is carried out in this work. We elucidate all the pathways lead...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050042/ https://www.ncbi.nlm.nih.gov/pubmed/35497244 http://dx.doi.org/10.1039/c9ra10760f |