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Synthesis and characterization of hydroxyl-terminated butadiene-end-capped polyisobutylene and its use as a diol for polyurethane preparation

Hydroxyl-terminated telechelic polyisobutylene (PIB) was prepared through living cationic polymerization. A living PIB chain was formed using the t-Bu-m-DiCuOMe/TiCl(4) initiating system and then capped with 1,3-butadiene (BD) to prepare chlorine-terminated telechelic PIB. The chlorine-terminated te...

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Detalles Bibliográficos
Autores principales: Wu, Kangda, Wu, Yibo, Huang, Shan, Chen, Zhifei, Wang, Hao, Shang, Yuwei, Li, Shuxin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050137/
https://www.ncbi.nlm.nih.gov/pubmed/35497236
http://dx.doi.org/10.1039/d0ra00132e