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Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO(2) with hydrosilanes

The iridium complex [Ir(μ-CF(3)SO(3))(κ(2)-NSi(Me2))(2)](2) (3) (NSi(Me2) = {4-methylpyridine-2-yloxy}dimethylsilyl) has been prepared by reaction of [Ir(μ-Cl)(κ(2)-NSi(Me2))(2)](2) (1) with two equivalents of AgCF(3)SO(3). The solid structure of 3 evidenced its dinuclear nature, being a rare exampl...

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Detalles Bibliográficos
Autores principales: Guzmán, Jefferson, García-Orduña, Pilar, Lahoz, Fernando J., Fernández-Alvarez, Francisco J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050147/
https://www.ncbi.nlm.nih.gov/pubmed/35497254
http://dx.doi.org/10.1039/d0ra00204f