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Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO(2) with hydrosilanes
The iridium complex [Ir(μ-CF(3)SO(3))(κ(2)-NSi(Me2))(2)](2) (3) (NSi(Me2) = {4-methylpyridine-2-yloxy}dimethylsilyl) has been prepared by reaction of [Ir(μ-Cl)(κ(2)-NSi(Me2))(2)](2) (1) with two equivalents of AgCF(3)SO(3). The solid structure of 3 evidenced its dinuclear nature, being a rare exampl...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050147/ https://www.ncbi.nlm.nih.gov/pubmed/35497254 http://dx.doi.org/10.1039/d0ra00204f |