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Tetrafluoroaryl azide as an N-terminal capping group for click-to-dissolve diphenylalanine hydrogels

The synthesis of a bioorthogonal-responsive low molecular weight diphenylalanine (PhePhe)-based hydrogel that is capped with a 4-azido-2,3,5,6-tetrafluorobenzyl carbamate self-immolative linker is reported. The hydrogelator (AzF(4)-PhePhe) generates a stable hydrogel at 0.1 wt%, and rapidly reacts w...

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Detalles Bibliográficos
Autores principales: Dadhwal, Sumit, Fairhall, Jessica M., Hook, Sarah, Gamble, Allan B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050152/
https://www.ncbi.nlm.nih.gov/pubmed/35497212
http://dx.doi.org/10.1039/d0ra01013h