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Formation of cyclic structures in the cationic ring-opening polymerization of 1,3-dioxolane

The cationic ring-opening polymerization of acetals is prone to cyclization of the polymer chains. This is also the case for the polymerization of 1,3-dioxolane. Literature states that this cyclization can be reduced by applying the Active Monomer mechanism, at least if no competition with the Activ...

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Detalles Bibliográficos
Autores principales: Coenen, Anna M. J., Harings, Jules A. W., Ghazanfari, Samaneh, Jockenhoevel, Stefan, Bernaerts, Katrien V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050153/
https://www.ncbi.nlm.nih.gov/pubmed/35497238
http://dx.doi.org/10.1039/d0ra00904k