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Polymorphism of Au(11)(PR(3))(7)Cl(3) clusters: understanding C–H⋯π interaction and C–H⋯Cl–C van der Waals interaction on cluster assembly by surface modification
The C–H⋯π interaction and the C–H⋯Cl–C van der Waals interaction play a crucial role in the crystallization of nanoclusters. In this paper, we present an example of a crystal system transformation of Au(11)(PR(3))(7)Cl(3) from monoclinic (M) to trigonal (T) by surface modification. Atomically-resolv...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050627/ https://www.ncbi.nlm.nih.gov/pubmed/35495341 http://dx.doi.org/10.1039/d0ra01288b |