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Polymorphism of Au(11)(PR(3))(7)Cl(3) clusters: understanding C–H⋯π interaction and C–H⋯Cl–C van der Waals interaction on cluster assembly by surface modification

The C–H⋯π interaction and the C–H⋯Cl–C van der Waals interaction play a crucial role in the crystallization of nanoclusters. In this paper, we present an example of a crystal system transformation of Au(11)(PR(3))(7)Cl(3) from monoclinic (M) to trigonal (T) by surface modification. Atomically-resolv...

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Detalles Bibliográficos
Autores principales: Qin, Chenwanli, Yuan, Qianqin, Li, Peng, Wang, Shuxin, Chen, Shuang, Zhu, Manzhou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050627/
https://www.ncbi.nlm.nih.gov/pubmed/35495341
http://dx.doi.org/10.1039/d0ra01288b

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