An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade

A modular and efficient method for constructing angular tri-carbocyclic architectures containing quaternary carbon center(s) from 1,3-dicycloalkylidenyl ketones is established, which involves an unconventional synergistic cascade of a Nazarov cyclization and two ring expansions. It features high sel...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yun-Peng, Fang, Kun, Tu, Yong-Qiang, Yin, Jun-Jie, Zhao, Qi, Ke, Tian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050659/
https://www.ncbi.nlm.nih.gov/pubmed/35484150
http://dx.doi.org/10.1038/s41467-022-29947-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050659/
https://www.ncbi.nlm.nih.gov/pubmed/35484150
http://dx.doi.org/10.1038/s41467-022-29947-5

Ejemplares similares