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Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes

A new synthetic method is described to construct 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions. Reactions of azobenzenes as nitrogen sources with phosphaalkynes as phosphorous counterparts in the presence of VCl(2)(thf)(2) as a catalyst afford the corre...

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Detalles Bibliográficos
Autores principales: Liang, Wenbin, Nakajima, Kazunari, Nishibayashi, Yoshiaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051379/
https://www.ncbi.nlm.nih.gov/pubmed/35492129
http://dx.doi.org/10.1039/d0ra02503h