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Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
A new synthetic method is described to construct 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions. Reactions of azobenzenes as nitrogen sources with phosphaalkynes as phosphorous counterparts in the presence of VCl(2)(thf)(2) as a catalyst afford the corre...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051379/ https://www.ncbi.nlm.nih.gov/pubmed/35492129 http://dx.doi.org/10.1039/d0ra02503h |
| Sumario: | A new synthetic method is described to construct 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions. Reactions of azobenzenes as nitrogen sources with phosphaalkynes as phosphorous counterparts in the presence of VCl(2)(thf)(2) as a catalyst afford the corresponding 1,2,4-azadiphospholes. |
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