Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes

A new synthetic method is described to construct 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions. Reactions of azobenzenes as nitrogen sources with phosphaalkynes as phosphorous counterparts in the presence of VCl(2)(thf)(2) as a catalyst afford the corre...

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Detalles Bibliográficos
Autores principales: Liang, Wenbin, Nakajima, Kazunari, Nishibayashi, Yoshiaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051379/
https://www.ncbi.nlm.nih.gov/pubmed/35492129
http://dx.doi.org/10.1039/d0ra02503h
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author Liang, Wenbin
Nakajima, Kazunari
Nishibayashi, Yoshiaki
author_facet Liang, Wenbin
Nakajima, Kazunari
Nishibayashi, Yoshiaki
author_sort Liang, Wenbin
collection PubMed
description A new synthetic method is described to construct 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions. Reactions of azobenzenes as nitrogen sources with phosphaalkynes as phosphorous counterparts in the presence of VCl(2)(thf)(2) as a catalyst afford the corresponding 1,2,4-azadiphospholes.
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spelling pubmed-90513792022-04-29 Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes Liang, Wenbin Nakajima, Kazunari Nishibayashi, Yoshiaki RSC Adv Chemistry A new synthetic method is described to construct 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions. Reactions of azobenzenes as nitrogen sources with phosphaalkynes as phosphorous counterparts in the presence of VCl(2)(thf)(2) as a catalyst afford the corresponding 1,2,4-azadiphospholes. The Royal Society of Chemistry 2020-03-30 /pmc/articles/PMC9051379/ /pubmed/35492129 http://dx.doi.org/10.1039/d0ra02503h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Liang, Wenbin
Nakajima, Kazunari
Nishibayashi, Yoshiaki
Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
title Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
title_full Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
title_fullStr Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
title_full_unstemmed Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
title_short Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
title_sort synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051379/
https://www.ncbi.nlm.nih.gov/pubmed/35492129
http://dx.doi.org/10.1039/d0ra02503h
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AT nakajimakazunari synthesisof124azadiphospholederivativesbasedonvanadiumcatalyzed221cycloadditionreactionsofazobenzeneswithphosphaalkynes
AT nishibayashiyoshiaki synthesisof124azadiphospholederivativesbasedonvanadiumcatalyzed221cycloadditionreactionsofazobenzeneswithphosphaalkynes

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