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Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp(3))–H Functionalization via Radical and Cationic Intermediates
[Image: see text] The C(sp(3))–H bond oxygenation of the cyclopropane-containing mechanistic probes 6-tert-butylspiro[2.5]octane and spiro[2.5]octane with hydrogen peroxide catalyzed by manganese complexes bearing aminopyridine tetradentate ligands has been studied. Mixtures of unrearranged and rear...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052745/ https://www.ncbi.nlm.nih.gov/pubmed/35417154 http://dx.doi.org/10.1021/jacs.2c01466 |